Monoalkylation of C60 and C70 with Zn and active alkyl bromides.
| Author | |
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| Abstract | :
We report a convenient and simple solution-phase electron-transfer reaction of C(60) with zinc and alpha-bromoacetonitrile, alpha-bromo acetate esters, allyl bromide, benzyl bromide and alpha-bromo ketones in DMF, with which different types of monoalkylated C(60) derivatives can be prepared. When this method is employed with C(70), 2-carbomethoxymethyl-1,2-dihydro[70]fullerene (isomer 5a) is produced as one of the two 1,2-monoalkylated C(70) isomers, together with the first 5,6-monoalkylated C(70) derivative. |
| Year of Publication | :
2003
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| Journal | :
The Journal of organic chemistry
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| Volume | :
68
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| Issue | :
8
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| Number of Pages | :
3043-8
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| Date Published | :
2003
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| ISSN Number | :
0022-3263
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| URL | :
https://doi.org/10.1021/jo020563o
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| DOI | :
10.1021/jo020563o
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| Short Title | :
J Org Chem
|
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