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J.D. Tovar will be presenting a seminar titled Intra- and inter-molecular approaches to encourage energy transport in organic electronic materials. 

Abstract: Several emerging energy technologies require flexible and solution-processable organic-based electronic materials capable of specific degrees of energy transport in order to achieve desired functions.  The range of materials (and applications) is quite diverse, as exemplified by new materials that can facilitate photovoltaic, light emitting or transistor behavior.  The molecular requirements necessary to achieve these functions vary greatly, and this lecture will highlight fundamental structural considerations relevant to the design of materials that can foster or otherwise regulate efficient energy/charge migration. One aspect involves the use of unusual aromatic building blocks with relatively low degrees of resonance stabilization that can encourage the intramolecular electronic delocalization of charge carriers. Another aspect deals with alternative ways to control intramolecular delocalization of polymer charge carriers through “evolved aromaticity.”  A final aspect involves the control of intermolecular electronic delocalization through the use of water-soluble oligopeptides attached to pi-conjugated oligomers that self-assembly into fibrillar bioelectronic nanostructures containing internal pi-stacked electronic conduits. In all cases, the making, breaking and stacking of aromatic rings is of utmost importance.

Recent references

D. R. Levine, M. A. Siegler and J. D. Tovar, “Thiophene-fused borepins as directly functionalizable boron-containing -electron systems,” J. Am. Chem. Soc. 2014, 136, 7132-7139.

J. D. Tovar, “Prospecting in Hückel space: from Hinokitiol to non-benzenoid organic electronic materials,” Chem. Rec. (introductory essay for the Tetsuo Nozoe Autograph Book project), 2014, 14, 214-225.

J. D. Tovar, “Supramolecular construction of optoelectronic biomaterials,” Acc. Chem. Res. 2013, 46, 1527-1537.

A. M. Fraind, G. Sini, C. Risko, L. R. Ryzhkov, J.-L. Brédas and J. D. Tovar, “Charge delocalization through benzene, naphthalene, and anthracene bridges in pi-conjugated oligomers: an experimental and quantum chemical study,” J. Phys. Chem. B 2013, 117, 6304-6317.

Faculty Host: Dr. John Anthony